Cadmium Dimethyl Sulfoxide Thiocyanate NLO Crystal: Structural, Optical and Thermal Properties

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S. Karthick, A. Albert Irudayaraj, A. Dhayal Raj, R. Vinayagamoorthy, (2017). Cadmium Dimethyl Sulfoxide Thiocyanate NLO Crystal: Structural, Optical and Thermal PropertiesMechanics, Materials Science & Engineering, Vol 9. doi:10.2412/mmse.66.68.799

Authors: S. Karthick, A. Albert Irudayaraj, A. Dhayal Raj, R. Vinayagamoorthy

ABSTRACT. Cadmium Dimethyl Sulfoxide Thiocyanate (CDST) organometallic crystal was grown from aqueous solution. The grown CDST crystals are characterized by single X-ray diffraction for structural analysis. Fourier Transformation Infrared analysis confirms the presence of functional groups in the CDST. UV- Visible analysis reveals that CDST is about 90% transparent in the entire visible region and UV lower cutoff wavelength is 236 nm. TGA and DTA studies reveal the physicochemical stability of the CDST and NLO study by Kurtz – Perry powder technique reveals that the CDST exhibits emission of green light and the second harmonic generation efficiency of CDTS was 1.2 times that of KDP.

Keywords: Organometallic crystal, FTIR, UV-Vis, TG/DTA, NLO.

DOI 10.2412/mmse.66.68.799

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