Cite the paper
I. Md. Zahid, C. Amirtha Kumar, R. Mohan Kumar (2017). Crystal Growth, Spectral and Optical Studies of 2-Aminoanilinium Benzoate Single Crystal. Mechanics, Materials Science & Engineering, Vol 9. doi:10.2412/mmse.59.74.247
Authors: I. Md. Zahid, C. Amirtha Kumar, R. Mohan Kumar
ABSTRACT. The proton transfer or H-bonded complex of 2-aminoanilinium benzoate (OPDB) was synthesized from O-phenylenediamine as donor and benzoic acid as acceptor. OPDB crystals were grown by solution growth technique. The cell parameters and crystalline perfection of the grown crystal were studied by single crystal and powder X-ray diffraction analyses. The title compound was classified into orthorhombic crystal system with non-centrosymmetric P212121 space group. FTIR spectral analysis revealed the existence of functional groups and their corresponding vibrational modes have been assigned. The optical transmission properties of the crystal were studied by UV–Vis spectral analysis. Laser induced damage threshold of the grown crystal was estimated using Nd:YAG laser source. The second harmonic generation efficiency of the grown crystal was studied by Kurtz-Perry test.
Keywords: Growth from solution, X-ray diffraction, nonlinear optics
 P.N.Prasad, D.J.Williams, Introduction to Nonlinear Optical Effects in Organic Molecules and Polymers, Wiley, New York, 1991.
 D.S.Chemla, J.Zyss, Eds. Nonlinear Optical Properties of Organic Molecules and Crystals; Academic Press, NewYork, 1987.
 P.Vijayakumar, G.Anandha Babu, P.Ramasamy, Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluene sulphonate, Materials Research Bulletin 47 (2012) 957–962, doi: 10.1016/j.materresbull.2012.01.011
 N. Vijayan, R. Babu, R. Gopalakrishnan, P. Ramasamy, growth and characterization of Benzimidazole single crystals: a nonlinear optical material, J. Cryst. Growth 262, 2004, 490-498.DOI: 10.1016/j.crysgro.2003.08.082
 H. Nakatani, W.R. Bosenberg, L.K. Cheng, Appl. Phys. Lett. 53 , 1988 , 2587-2591. DOI:10.1063/1.100535
 Cara. C. Evans, M. Bagieu- Beucher, R. Masse, J. F. Nicoud, Chem. Mater. 10, 1998, 847-854. DOI:10.1021/cm970618.
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