Cite the paper
A. Hemalatha, K. Deepa, A. Venkatesan, S. Senthil (2017). Growth and Characterization of a Novel Nonlinear Optical Single Crystal of l-Isoleucinium Hydrogen Maleate Hemihydrate. Mechanics, Materials Science & Engineering, Vol 9. doi:10.2412/mmse.85.63.511
Authors: A. Hemalatha, K. Deepa, A. Venkatesan, S. Senthil
ABSTRACT. L- Isoleucinium Hydrogen Maleate Hemihydrate (LIM), a nonlinear optical single crystal was grown from aqueous medium by the slow evaporation method at room temperature. The powder XRD analysis reveals that the grown crystal is belongs to monoclinic system with the space group P21. The presence of various functional groups in the LIM is confirmed by FT-IR and FT-RAMAN spectroscopy. The second harmonic generation (SHG) efficiency measurements reveal that the LIM is suitable for nonlinear optical (NLO) applications. Thermo-gravimetric and differential thermo gravimetric analysis reveal the thermal stability of the material. The optical transparency has been studied using UV-Vis-NIR spectroscopy and the band gap energy were found out from the absorption studies. The third order nonlinear behavior has been investigated using Z-Scan technique.
Keywords: nonlinear optical single crystal, monoclinic system, XRD analysis, NIR spectroscopy.
 Sergey G. Arkhipov, Denis A. Rychkov, Alexey M. Pugachevc and Elena V.Boldyrevaa, Structural Chemistry (Research Paper), New hydrophobic L-amino acid salts: maleates of L-leucine, L-isoleucine and L-norvaline, Journal of Acta Crystal C, 2015, C17, 1-9. DOI. org/10.1107/S2053229615010888.
 C. Alosious Gonsago, Helen Merina Albert, S. Janarthanan, and A. Joseph Arul Pragasam, Crystal Growth and Characterization of an Organic Nonlinear Optical Material: L-Histidinium Maleate,(LHM), International Journal of Applied Physics and Mathematics, November 2012,Vol.2, No. 6, DOI: 10.7763/IJAPM.2012.V2.150
 G. Ramasamy, Subbiah, Meenakshisundaram, Studies on amino acid picrates: Crystal growth, structure and characterization of a new nonlinear optical material l-isoleucinium picrate, Journal of optic communication, 2014, 125, 4422-4426. DOI10.1016/j.ijleo.2014.02.036
 Mohd Shkir, Haider Abbas, Physico chemical properties of L-asparagine L-tartaric acid single crystals: A new nonlinear optical material, Journal of Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, (2014), 118, 172–176, DOI 10.1016/j.saa.2013.08.086.
 S. Masilamani, A. Mohamed Musthafa, P. Krishnamurthi, Synthesis, Growth and characterisation of a semiorganic nonlinear optical material: L-threonine cadmium chloride single crystals, Arabian Journal of Chemistry, 2014, DOI 10.1016/j.arabjc.2014.06.003.
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